Volume 13, Issue 2 (International Journal of Optics and Photonics (IJOP) Vol 13, No 2, Summer-Fall 2019)                   IJOP 2019, 13(2): 189-198 | Back to browse issues page

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Rezaie Kahkhaie V, Yousefi M H, Darbany S M R, Mobashery A. Unification of Surface Enhanced Raman Spectroscopy of Dyes Using One Pot Synthesized Stabilized Ag Nanoparticles. IJOP. 2019; 13 (2) :189-198
URL: http://ijop.ir/article-1-374-en.html
Nano-Physics Center, Dept. of Physics, Malek Ashtar University of Technology
Abstract:   (346 Views)

stabilized Ag Nanoparticles (NPs) were synthesized using Lee-Meisel method under three different conditions in an oil bath. UV-Vis spectroscopy of the Ag NPs showed a Localized Surface Plasmon (LSP) band around 430 nm, indicating Ag NPs had a size range around 40 nm. To fabricate a surface Enhanced Raman Spectroscopy (SERS) substrate, LSP properties of Ag NPs was employed with the goal of detecting Rhodamine 6G dye. SERS spectrum was recorded by using 180 degrees, back-scatter Raman configuration in a custom-made mount. The results showed that ideal Ag NPs agglomeration condition had been achieved by applying centrifuging process and due to this, adding NaCl salt to the SERS substrate was found to be unnecessary. The optimum rate of tri-sodium citrate versus silver nitrate and its influence on UV-Vis and SERS spectra was determined. It was understood that in order to obtain a uniform SERS intensity profile, employing a heater-stirrer instead of an oil bath alongside controlling the atmospheric condition and also drying the substrate in the Argon gas medium are the most necessary conditions for Ag NPs synthesize. The novelty point is obtained when SERS of R6G on a certain substrate, immediately after fabrication and after one month, were compared with a bare R6G dye substrate which, have revealed exceptional performance.


Keywords: SERS, Ag NPs, Lee-Meisel, LSP
Full-Text [PDF 661 kb]   (123 Downloads)    
Type of Study: Research | Subject: Special
Received: 2018/12/18 | Revised: 2019/07/19 | Accepted: 2019/08/23 | Published: 2019/12/27

1. Xi. Hou, Xi. Zhang, Sh. Chen, H. Kang, and W. Tan, "Facile synthesis of Ni/Au, Ni/Ag hybrid magnetic nanoparticles new active substrates for surface enhanced Raman scattering," Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol. 403, pp. 148-154, 2012. [DOI:10.1016/j.colsurfa.2012.04.005]
2. J. Shen, Y. Zhu, Xi. Yang, J. Zong, and Ch. Li, "Multifunctional Fe3O4@Ag/SiO2/Au Core-shell Microspheres as a Novel SERS-Activity Label via Long-Range Plasmon Coupling," Langmuir, Vol. 29, pp. 690-695, 2013. [DOI:10.1021/la304048v]
3. V. Uzayisenga, Xi.-D. Lin, L.-M. Li, J.R. Anema, Zh.-L. Yang, Y.-F. Huang, H.-X. Lin, S.-B. Li, J.-F. Li, and Zh.-Q. Tian, "Synthesis, Characterization, and 3D-FDTD, Simulation of Ag@SiO2 Nanoparticles for Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy," Langmuir, Vol. 28, pp. 9140-9146, 2012. [DOI:10.1021/la3005536]
4. Y. Wan, Zh. Guo, X. Jiang, K. Fang, X. Lu, Y. Zhang, and N. Gu, "Quasi-spherical silver nanoparticles: Aqueous synthesis and size control by the seed-mediated Lee-Meisel method," Adv. Colloid Interface Sci. Vol. 394, pp. 263-268, 2013. [DOI:10.1016/j.jcis.2012.12.037]
5. D. Philip, K.G. Gopchandran, C. Unni, and K.M. Nissamudeen, "Synthesis, characterization and SERS activity of Au-Ag nanorods," ‎Spectrochim. Acta A, Vol. 70, pp. 780-784, 2008. [DOI:10.1016/j.saa.2007.09.016]
6. W. Meng, F. Hu, Xi. Jiang, and L. Lu, "Preparation of silver colloids with improved uniformity and stable surface-enhanced Raman scattering," Nanoscale Res. Lett. Vol. 10, pp. 34-42, 2015. [DOI:10.1186/s11671-015-0746-1]
7. M. Shanthil, H. Fathima, and K. George Thomas, "Cost-Effective Plasmonic Platforms: Glass Capillaries Decorated with Ag@SiO2 Nanoparticles on Inner Walls as SERS Substrates," ACS Appl. Mater. Interfaces, Vol. 9, pp. 19470-19477, 2017. [DOI:10.1021/acsami.6b12478]
8. Qi Shao, F. Liao, and A. Ruotolo, "Magnetic-Polaron-Induced Enhancement of Surface Raman Scattering," Sci. Rep. Vol. 6, pp. 19025 (1-7), 2016. [DOI:10.1038/srep19025]
9. J. Li, S.K. Cushing, P. Zheng, T. Senty, F. Meng, A.D. Bristow, A. Manivannan, and N. Wu, "Solar Hydrogen Generation by a CdS-Au-TiO2 Sandwich Nanorod Array Enhanced with Au Nanoparticle as Electron Relay and Plasmonic Photosensitizer," ‎J. Am. Chem. Soc. Vol. 136, pp. 8438-8449, 2014. [DOI:10.1021/ja503508g]
10. L. Polavarapu, A.L. Porta, S. M. Novikov, M. Coronado-Puchau , and L. M. Liz-Marzán, "Pen-on-Paper Approach Toward the Design of Universal Surface Enhanced Raman Scattering Substrates," Small, Vol. 10, pp. 3065-3071, 2014. [DOI:10.1002/smll.201400438]
11. Ch. Fan, "Tunable SERS effect of the silver rod and magnetite nanocomposite with different magnetic field and aspect ratios," J. Opt. Vol. 45, pp. 307-311, 2016. [DOI:10.1007/s12596-015-0297-y]
12. J. Kimling, M. Maier, B. Okenve, V. Kotaidis, H. Ballot, and A. Plech, "Turkevich Method for Gold Nanoparticle Synthesis Revisited," J. Phys. Chem. B, Vol. 110, pp. 15700-15707, 2006. [DOI:10.1021/jp061667w]
13. M. Lismont, C. A. Páez, and L. Dreesen, "A one-step short-time synthesis of Ag@SiO2 core-shell nanoparticles," Adv. Colloid Interface Sci. Vol. 447, pp. 40-49, 2015. [DOI:10.1016/j.jcis.2015.01.065]
14. Y. Qin, Xi. Ji, J. Jing, H. Liu, H. Wu, and W. Yang, "Size control over spherical silver nanoparticles by ascorbic acid reduction," Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol. 372, pp. 172-176, 2010. [DOI:10.1016/j.colsurfa.2010.10.013]
15. S. Hong and Xi. Li, "Optimal Size of Gold Nanoparticles for Surface-Enhanced Raman Spectroscopy under Different Conditions," J. Nanomater. Vol. 2013, pp. 790323 (1-9), 2013. [DOI:10.1155/2013/790323]
16. K.G. Stamplecoskie and J.C. Scaiano, "Optimal Size of Silver Nanoparticles for Surface-Enhanced Raman Spectroscopy," J. Phys. Chem. C, Vol. 115, pp. 1403-1409, 2011. [DOI:10.1021/jp106666t]
17. X. Wang, Y. Du, Q. Li, T. Wu, H. Hu, Y. Xu, H. Zhang, and Y. Pan, "Fabrication of uniform substrate based on silver nanoparticles decorated glycidyl methacrylate-ethylene dimethacrylate porous material for ultrasensitive surface-enhanced Raman scattering detection," J. Raman Spectros. Vol. 45, pp. 47-53, 2014. [DOI:10.1002/jrs.4418]
18. M. Wahadoszamen, A. Rahaman, N. M. R. Hoque, A. Talukder, K. M. Abedin, and A. F. M. Yusuf Haider, "Laser Raman Spectroscopy with Different Excitation Sources and Extension to Surface Enhanced Raman Spectroscopy," J. Spectrosc. Vol. 2015, pp. 895317 (1-8), 2015. [DOI:10.1155/2015/895317]
19. A.M. Michaels, M. Nirmal, and L.E. Brus, "Surface Enhanced Raman Spectroscopy of Individual Rhodamine 6G Molecules on Large Ag Nanocrystals," J. Am. Chem. Soc. Vol. 121, pp. 9932-9939, 1999. [DOI:10.1021/ja992128q]
20. C.P. León, "Vibrational Spectroscopy of Photosensitizer Dyes for Organic Solar Cells," Cuvillier, PhD Thesis, Dep. Physics, University of Bayreuth, Bayreuth, Lebanon, 2006.

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