Showing 3 results for Silver Nanoparticle
Bahareh Morovvati , Rasoul Malekfar,
Volume 13, Issue 2 (12-2019)
Abstract
The active substrates in surface enhanced Raman scattering (SERS) spectroscopy were prepared through self-assembly of nanoparticles on functionalized glasses. Colloidal silver nanoparticles (Ag NPs) were prepared chemically in two different sizes by reduction of AgNO3 using trisodium citrate and sodium borohydride. Gold–silver core–shell nanoparticles were also prepared to compare between the optical behaviors of their silver shell and Ag NPs. Absorption spectra of nanoparticles were measured by ultraviolet–visible (UV–Vis.) spectroscopy, and their approximate sizes were determined by dynamic light scattering (DLS). The core–shell nanoparticles were approximately the same size as the largest Ag NPs (35 nm) and had the same maximum absorption wavelength. The potential of these substrates for detection applications was investigated with 1 M and 0.1 mM solutions of Raman-active molecule of crystal violet (CV) dye. The Raman enhancement signal was recorded for 0.1 mM solution with 532 nm laser wavelength, and the obtained spectra enhancement factor (EF) was calculated. EF values indicated that although the silver and gold–silver core–shell nanoparticles had the same surface plasmon resonance, the substrate with smaller Ag NPs had the highest enhancement factor compared to other substrates, which was 9.5´103, and the core–shell substrate even had a slightly lower enhancement factor in compare with the large Ag NPs.
Bita Azemoodeh Afshar, Akbar Jafari, Rahim Naderali, Mir Maqsood Golzan,
Volume 16, Issue 2 (7-2022)
Abstract
In this study, we investigated the production of silver nanoparticles by pulsed Nd: YAG laser ablation with λ=532nm in distilled water. The sodium citrate used to control the size of nanoparticles (Nps). The sample containing Ag NPs was characterized by linear absorption spectroscopy (UV-Visible spectroscopy) and transmission electron microscopy (TEM observation). The behavior of nonlinear optical properties of silver nanoparticles was studied using the Z-Scan method at two optimum numbers of the laser pulses and four optimum laser energy densities. In the Z-Scan method, the nonlinear thermal properties of Ag NPs were investigated under exposure to nanosecond laser pulse at λ=532nm. They were gained by fitting theoretical and experimental data. The values of the nonlinear refractive index (n2) and the nonlinear absorption coefficient (β ) were compared concerning to two optimum numbers and four optimum energy densities. The results of the nonlinear refractive index showed a negative value for each sample, this means that samples act as a divergent lens, and the thermal self-defocusing effect can be the main factor of nonlinear behavior. Following the comparison of two quantities, n2 and β , we found that the nonlinear refractive index increased when the number of laser pulses light increased. In addition, the nonlinear absorption coefficient decreased when the number of laser pulses light increased. As a result, the application of these Ag NPs for optical switching devices was investigated, which demonstrated that the large Ag NPs are applicable tools for optical switching devices.
Neda Roostaei, Seyedeh Mehri Hamidi,
Volume 17, Issue 2 (6-2023)
Abstract
Color vision deficiency (CVD), or color blindness, is a prevalent ocular disorder that hinders the recognition of different colors, affecting many people worldwide (8−10% of males and 0.4−0.5% of females). Recently, there has been a significant focus on plasmonic nanostructures as an alternative to chemical dyes for managing color blindness due to their remarkable characteristics and the tunability of plasmonic resonances. In this work, the plasmonic glasses based on silver nanoparticles with a TiO2 thin layer coating were fabricated using the sputtering technique and proposed for blue-yellow (tritanopia) CVD management. The proposed plasmonic glasses based on silver nanoparticles are more selective than commercial Enchroma glasses because of the tunability of plasmonic properties of silver nanoparticles by controlling their morphology, which provides insights for applications of color vision deficiency improvement. Also, the antibacterial activity of the proposed plasmonic glasses based on silver nanoparticles was investigated against E. coli and S. aureus bacteria, which have exhibited effective antibacterial properties. The results indicate that the silver nanoparticle-based glasses not only aid in tritanopia management but also offer potential for antibacterial applications such as implant coatings.