Mrs. Hajar Ghanbari, Dr. Rasoul Sarraf-Mamoory, Prof. Jamshid Sabbagh Zadeh, Mr. Ali Chehrghani, Dr. Rasoul Malekfar,
Volume 7, Issue 2 (8-2013)
Abstract
In this study, Highly Oriented Pyrolytic Graphite was ablated in various polar and nonpolar solvents by Q-switched neodymium: yttrium-aluminum-garnet laser (wavelength=1064 nm, frequency=2 kHz, pulse duration=240 ns). Then, the products were examined using Scanning Electron Microscopy and UV-Vis spectroscopy. The images showed that different carbon structures such as cauliflower-like structures in benzene, spiral integrated forms in toluene, organic integrated networks in hexane, and nanoparticles in ethanol were formed. In n-methyl-2-pyrrolidone (NMP), sheets and bulk deformed structures were seen. Also, in Dimethylacetamide, particles in different stages of growth could be detected. The nonlinear optical absorption (NLA) behaviors of the products were investigated by exposing them to a 532 nm nanosecond laser using the Z-scan technique. The saturated NLA coefficient, obtained from structures of NMP and hexane-based synthesized samples, are 1.1×10-8 and 2.4×10-8 cm W-1, respectively. The saturable absorption responses of these samples were switched to the reverse saturable absorption responses in the other synthesis mediums. The maximum nonlinear absorption coefficient of 10.2×10-8 cm W 1 was measured for spiral integrated superstructures, produced in the toluene medium.
Reza Pourahmad, Sheila Shahidi, Amirhossein Sari, Mohammadreza Hantezadeh,
Volume 17, Issue 1 (1-2023)
Abstract
In this research, an attempt is made to approach a specific type of carbon, such as graphene or carbon nanotubes by using pulsed laser ablation technique in deionized water environment with changing the laser factors such as wavelength and fluence. Nd:YAG laser with two wavelengths of 1064 and 532 nm and three fluence of 0.8, 1 and 1.2 J/cm2 were selected that number of pulses was 5000 with a frequency of 10 Hz to be irradiated on the graphite target at about 10 minutes. The medium was distilled water. Graphite was located in the 40 ml of distilled water.
The effects of wavelength and fluence of the laser have been experimentally investigated on types of carbon characteristics with different analysis such as Raman scattering spectrum, FE-SEM images, UV–Vis-NIR spectrum and X-ray diffraction (XRD). By using the mentioned analysis, the type of synthesized nano carbon is studied.
This study evaluates the effects of the pulse energy and laser wavelength on properties of synthesized carbon nanoparticle in laser ablation method in medium of distilled water.
